Inputs of iron,manganese and aluminium to surface waters of the Northeast Atlantic Ocean and the European continental shelf     

Jeroen T.M. de Jong  Marie Boyé  Maria D. Gelado-Caballero  Klaas R. Timmermans  Marcel J.W. Veldhuis  Rob F. Nolting  Constant M.G. van den Berg  Hein J.W. de Baar 《Marine Chemistry》2007

Dissolved Fe, Mn and Al concentrations (dFe, dMn and dAl hereafter) in surface waters and the water column of the Northeast Atlantic and the European continental shelf are reported. Following an episode of enhanced Saharan dust inputs over the Northeast Atlantic Ocean prior and during the cruise in March 1998, surface concentrations were enhanced up to 4 nmol L^− 1 dFe, 3 nmol L^− 1 dMn and 40 nmol L^− 1 dAl and returned to 0.6 nmol L^− 1 dFe, 0.5 nmol L^− 1 dMn and 10 nmol L^− 1 dAl towards the end of the cruise three weeks later. A simple steady state model (MADCOW, [Measures, C.I., Brown, E.T., 1996. Estimating dust input to the Atlantic Ocean using surface water aluminium concentrations. In: Guerzoni. S. and Chester. R. (Eds.), The impact of desert dust across the Mediterranean, Kluwer Academic Publishers, The Netherlands, pp. 301–311.]) was used which relies on surface ocean dAl as a proxy for atmospheric deposition of mineral dust. We estimated dust input at 1.8 g m^− 2 yr^− 1 (range 1.0–2.9 g m^− 2 yr^− 1) and fluxes of dFe, dMn and dAl were inferred. Mixed layer steady state residence times for dissolved metals were estimated at 1.3 yr for dFe (range 0.3–2.9 yr) and 1.9 yr for dMn (range 1.0–3.8 yr). The dFe residence time may have been overestimated and it is shown that 0.2–0.4 yr is probably more realistic. Using vertical dFe versus Apparent Oxygen Utilization (AOU) relationships as well as a biogeochemical two end member mixing model, regenerative Fe:C ratios were estimated respectively to be 20 ± 6 and 22 ± 5 μmol Fe:mol C. Combining the atmospheric flux of dFe to the upper water column with the latter Fe:C ratio, a ‘new iron’ supported primary productivity of only 15% (range 7%–56%) was deduced. This would imply that 85% (range 44–93%) of primary productivity could be supported by regenerated dFe. The open ocean surface data suggest that the continental shelf is probably not a major source of dissolved metals to the surface of the adjacent open ocean. Continental shelf concentrations of dMn, dFe, and to a lesser extent dAl, were well correlated with salinity and express mixing of a fresher continental end member with Atlantic Ocean water flowing onto the shelf. This means probably that diffusive benthic fluxes did not play a major role at the time of the cruise.  相似文献   

Isogeometric finite element analysis of poroelasticity     

Faisal Irzal  Joris J. C. Remmers  Clemens V. Verhoosel  René de Borst 《国际地质力学数值与分析法杂志》2013,37(12):1891-1907

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Process-based modeling of the overflow-induced growth of erosional channels     

Thieu Quang Tuan  Marcel J.F. Stive  Henk Jan Verhagen  Paul J. Visser 《Coastal Engineering》2008

A new process-based approach is introduced for a more efficient computation of the overflow-induced growth of an erosional channel in a non-cohesive homogeneous narrow landmass such as the breach growth in a sand-dike. The approach is easy to incorporate in a 1D/2DV morphodynamic model to compute the channel growth both vertically and laterally.  相似文献   

Looking beneath the Stawell and Bendigo zones in Victoria,Australia: a view through the granite window     

J. D. Clemens 《Australian Journal of Earth Sciences》2020,67(2):175-200

Abstract

Information, mainly from the granitic and silicic volcanic rocks in the Stawell, Bendigo and Melbourne structural zones in the state of Victoria, shows that the sources of both the S- and I-type rocks of the Stawell and Bendigo zones (SBZ) contrast in ages and chemistry with the sources of similar granitic rocks in the Melbourne Zone, consistent with the absence of the mainly Proterozoic Selwyn Block beneath most of the SBZ. Below a mid-crustal décollement in the SBZ, the crust is evidently highly variable and possibly includes thinned Proterozoic crust. There is geochronological evidence for ca 400 and ca 370?Ma granulite-grade metamorphic events here, and, after this double bout of metamorphism, and depletion in the silicic melt component, the constituents of the entire deep crust of the SBZ would have densities similar to those of overlying, much lower-grade Cambrian metabasaltic to boninitic rocks. Thus, granitic magmas may have formed here by partial melting of a variety of rock types, probably with back-arc affinities, with ages that may extend back to the Proterozoic. Therefore, the basement of the SBZ is unlikely to consist solely of thick ocean-floor rocks, as in some current interpretations.

1. KEY POINTS

2. The sources of the Devonian granitic rocks of the Stawell and Bendigo zones (SBZ) contrast in ages and chemistry with those of the Melbourne Zone granites.

3. Two Devonian granulite-facies events left the melt-depleted deep SBZ crust with densities similar to those of overlying Cambrian metabasaltic rocks.

4. The SBZ Devonian granitic magmas probably formed by partial melting of heterogeneous Proterozoic to Cambrian arc-related crust, below the mid-crustal décollement.

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A New Natural Secondary Reference Material for Garnet U-Pb Dating by TIMS and LA-ICP-MS     

Namık Aysal  Marcel Guillong  Tamara Bayanova  Mayuko Fukuyama  Nicole Leonard  İsak Yılmaz  Elif Varol  Fatma Şişman Tükel  Yusuf Kaan Kadıoğlu  Nurullah Hanilçi  Fulya Uzun  Ersin Kaygısız 《Geostandards and Geoanalytical Research》2023,47(2):297-310

Gem quality andradite-rich garnet (IUC-1), obtained from the Miocene trachyte dome near Ankara city (Turkey), has been identified as a potential natural secondary reference material for U-Pb dating. In this study, U-Pb dating was performed in five different laboratories using isotope dilution TIMS and laser ablation ICP-MS to determine the homogeneity of euhedral garnet crystals. The U-Pb ID-TIMS data for IUC-1 yielded ²⁰⁷Pb/²³⁵U and ²⁰⁶Pb/²³⁸U ages of 20.9 ± 0.4 and 20.6 ± 0.8 Ma respectively, and these values are consistent with U-Pb LA-ICP-MS analyses, in which different garnet crystals yielded ages of 20.8 ± 0.1, 20.7 ± 0.1, 20.7 ± 0.2 and 20.2 ± 0.1 Ma. An andradite (IUC-2) from the Serçeören wollastonite skarn (Turkey) can be used as a secondary reference material provided detailed imaging of the crystals is undertaken. ID-TIMS data yielded ²⁰⁷Pb/²³⁵U and ²⁰⁶Pb/²³⁸U ages of 20.4 ± 0.4 and 20.9 ± 1.0 Ma respectively, and yielded U-Pb ages on different grains of 20.5 ± 0.1, 20.7 ± 1.0, 20.8 ± 1.7 and 20.9 ± 1.6 Ma. The assigned weighted mean age of IUC-1 (20.4 ± 0.5 Ma, 2s) is proposed as a 2023 reference value. IUC-1 garnet is expected to contribute significantly to rapidly developing garnet geochronology in the near future.  相似文献   

Pb-concentrations and Pb-isotope ratios in soils collected along an east–west transect across the United States     

Clemens Reimann  David B. Smith  Laurel G. Woodruff  Belinda Flem 《Applied Geochemistry》2011,26(9-10):1623-1631

Analytical results for Pb-concentrations and isotopic ratios from ca. 150 samples of soil A horizon and ca. 145 samples of soil C horizon collected along a 4000-km east–west transect across the USA are presented. Lead concentrations along the transect show: (1) generally higher values in the soil A-horizon than the C-horizon (median 21 vs. 16.5 mg/kg), (2) an increase in the median value of the soil A-horizon for central to eastern USA (Missouri to Maryland) when compared to the western USA (California to Kansas) (median 26 vs. 20 mg/kg) and (3) a higher A/C ratio for the central to eastern USA (1.35 vs. 1.14). Lead isotopes show a distinct trend across the USA, with the highest ²⁰⁶Pb/²⁰⁷Pb ratios occurring in the centre (Missouri, median A-horizon: 1.245; C-horizon: 1.251) and the lowest at both coasts (e.g., California, median A-horizon: 1.195; C-horizon: 1.216). The soil C-horizon samples show generally higher ²⁰⁶Pb/²⁰⁷Pb ratios than the A-horizon (median C-horizon: 1.224; A-horizon: 1.219). The ²⁰⁶Pb/²⁰⁷Pb-isotope ratios in the soil A horizon show a correlation with the total feldspar content for the same 2500-km portion of the transect from east-central Colorado to the Atlantic coast that shows steadily increasing precipitation. No such correlation exists in the soil C horizon. The data demonstrate the importance of climate and weathering on both Pb-concentration and ²⁰⁶Pb/²⁰⁷Pb-isotope ratios in soil samples and natural shifts thereof in the soil profile during soil-forming processes.  相似文献   

Klimazeugen aus dem jüngsten Präkambrium und Unterkambrium in S-Marokko     

Dipl.-Geol. Clemens Marzela 《International Journal of Earth Sciences》1981,70(2):473-479

Zusammenfassung In Gesteinen des jüngsten Präkambriums und Unterkambriums (mit einer Diskordanz nach dem pC III) sind im Antiatlas Marokkos wiederholt Anzeichen für eine Sedimentation bei warmem (semiarid bis arid) Klima zu finden. Klimaindikatoren sind Rotsedimente, CaSO₄- und NaCl-Pseudomorphosen sowie Sedimente vom Sabkha-Typ.Paläomagnetische Daten weisen zu dieser Zeit auf Südpolpositionen in diesem Gebiet hin.Vereisungsrelikte in Nachbargebieten entsprechen möglicherweise einer Sedimentationslücke nach dem pC III im Antiatlas.

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In the Antiatlas region of Morocco rocks of Late-Precambrian and Lower-Cambrian age (with a discordance after the pC III) show evidence for sedimentation under warm (semiarid to arid) climate. Climate indicators are redbeds, sabkha-sediments and pseudomorphoses after CaSO₄ and NaCl.Paleomagnetic data showed that at this time southpole positions were distributed in this area.In nearby regions documents of glaciation are possibly correspondend with a time of non-sedimentation after the pC III in the Antiatlas.

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Résumé Les roches du Précambrien supérieur et du Cambrien inférieur de l'Antiatlas du Maroc (avec une discordance après le pC III) présentent de nombreuses évidences d'une sédimentation sous des conditions climatiques chaudes (semiarides à arides). Les indicateurs climatiques sont des couches rouges, des sédiments de sabkha et des pseudomorphoses de CaSO₄ et NaCl.Les études paléomagnétiques démontrent que l'emplacement du pôle sud se trouvait à cette époque dans cette même région.Les restes de glaciation dans les régions voisines paraissent corréspondre à une periode de nonsédimentation après le pC III dans l'Antiatlas.

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— III- ( ) . , CaSO₄ NaCl, Sabkha. , . , , — 800–900 .

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Hydrochemical Facies in a Tertiary Basin in the Milligan Canyon Area, Southwest Montana     

Noel C. Krothe  Marcel P. Bergeron 《Ground water》1981,19(4):392-399

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Structural control of the distribution of trace elements between silicates and hydrothermal solutions     

Marcel Volfinger  Jean-Louis Robert 《Geochimica et cosmochimica acta》1980,44(10):1455-1461

Over several years many partition coefficients have been measured between framework silicates, sheet silicates and hydrothermal solutions. Only trace alkaline cations are considered in the present work. It is well known that the difference between ionic radii of the trace cation and the major cation is replaces is not satisfactory for a good correlation with the partition coefficients P_X. A structural parameter δ_c is therefore defined, taking into consideration the adaptation of the trace cation to the cavity in which it occurs. This cavity may be the entire site of the major element, or a part of this site in the case of small cations, or a structural cavity located out of the alkali-ion site. The adaptation parameter δ_c is the difference between the ionic radius of the trace cation and the radius of that cavity. This paper shows that the partition coefficient P_X of the trace alkali-ion from the hydrothermal solution is an exponential function of the adaptation parameter δ_c, whatever the silicate may be.  相似文献   

Technique de prélèvement et d’analyse de gaz de fumerolles de volcans. Exemples d’analyses de gaz prélevés à la montagne Pelée (Martinique) et à la Grande Soufrière (Guadeloupe)     

René Fabre  Marcel Chaigneau 《Bulletin of Volcanology》1960,23(1):21-30

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